Investigating the Adsorption of Per- and Polyfluoroalkyl Substances on Amine-functionalized Mesoporous Carbons

Sammanfattning: Water pollution is a profound ecological concern, exerting detrimental effects on human well-being, ecological systems, and animal life. Among the emerging contaminants that critically influence water quality and have garnered substantial scientific interest in recent times are per- and polyfluoroalkyl substances (PFAS). It is crucial to investigate the de- velopment of an easy technique for PFAS detection and measurement that can be used for quick analysis. This thesis explores the possibility to use amine-functionalized mesoporous carbon as an adsorbent to develop a detection method based on sequential adsorption of per- and polyfluoroalkyl substances (PFAS) and a dye, Rose Bengal, onto the adsorbent. The hypothesis is that the concentration of non-adsorbed dye is dependent on the amount of PFAS present, making the color intensity of the remaining solution proportional to the PFAS concentration. Mesoporous carbon was chosen as the adsorbent due to their high specific surface area, providing a high adsorption capacity, and the potential to functionalize the surface with amine groups which will attract the PFAS. Rose Bengal was selected as a concentration indicator as it has been shown that it can be used as a proxy for PFAS. In this study, the most prevalent PFAS compounds, namely PFOA and PFOS, were investigated. Prior to testing, the adsorbent underwent characterization using diverse techniques to show the porosity and particle morphology. The adsorption experiments encompassed varying PFAS concentrations and a range of dye solutions to determine the detection range, the powder-to-solution ratio necessary for discernible differentiation, and the adsorption or saturation time for both PFAS and dye. This thesis concludes that it was not possible to detect neither PFOA nor PFOS in the range of 0.1 pg/mL to 1 μg/mL with the setup, even though Rose Bengal adsorption could be detected down to 0.6 μg/mL. It was further observed that amine-functionalized hard templated mesoporous carbon has a higher adsorption capacity compared to the soft templated material.